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One catalytic reform- ing process employs seven or so reactors with one of them Organo-main-group chemistry 2: boron, silicon and tin 47 Connections Building on: Conjugate addition ch10 ch23 Nucleophilic substitution at saturated carbon ch17 Controlling stereochemistry ch16, ch33, ch34 Oxidation, reduction, and protection ch24 Aldol reactions ch27 Controlling double bond geometry ch31 Rearrangements ch36ch37 Radicals ch39 Asymmetric synthesis ch45 Sulfur chemistry ch46 Arriving at: Main group elements in organic chemistry Boron is electrophilic because of a vacant orbital Hydroboration adds boron selectively Oxidation removes boron selectively Boron chemistry uses rearrangements Allyl B, Si, and Sn compounds are useful in synthesis Organo-B, -Si, and -Sn compounds can be used in asymmetric synthesis Silicon is more electrophilic than carbon Silicon stabilizes β carbocations Organo-tin compounds are like Si compounds but more reactive Tin is easily exchanged for lithium Looking forward to: Organometallic chemistry ch48 Polymerization ch52 Organic chemists make extensive use of the periodic table Although typical organic molecules, such as those of which all living things are composed, are con- structed from only a few elements (usually C, H, O, N, S, and P and, on occasion, Cl, Br, I, and a few more), there are very many other elements that can be used as the basis for reagents, catalysts, and as components of synthetic intermediates.

(xk mi,k)2 (13. Baltimore: Williams Wilkins, 1995:1(3).

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